Paper · 1987 · Chemical and Pharmaceutical Bulletin

Gardneria alkaloids. Part 14. The structure of gardfloramine and 18-demethyoxygardfloramine.

Shin-ichiro Sakai; Norio Aimi; Keiichi Yamaguchi; et al.

3
claims
5
verbatim quotes
6
citations
2
research areas
✓
Open access

Abstract

The structure of gardfloramine (1), which has been isolated as one of the minor bases from Gardneria multiflora, was determined by X-ray analysis. Its oxygenation pattern on the aromatic ring was revealed to be 9-methoxy-10, 11-methylenedioxy and is different from that of gardneramine. The structure of another minor alkaloid, 18-demethoxygardfloramine (2) was also determined by comparing the 13C-NMR spectra of 1 and 2.

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Claims 3

Observationobservedoriginal resultmeasured

Claim · model-written summary

X-ray analysis determined the structure of gardfloramine isolated from Gardneria multiflora.

Taxon
Gardneria multifloraGardneria multiflorae0
Outcome
structure of gardfloraminee0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Gardneria multiflora
Gardneria multiflora · TaxonXufanc · CC BY-SA 4.0 · Wikimedia Commons ↗

Verbatim

e0

“The structure of gardfloramine (1), which has been isolated as one of the minor bases from Gardneria multiflora, was determined by X-ray analysis.”

✓ located verbatim in the source · abstract, characters 0–146 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

Gardfloramine has a 9-methoxy-10, 11-methylenedioxy oxygenation pattern, different from gardneramine.

Taxon
Gardneria multifloraGardneria multiflorae1
Outcome
oxygenation pattern on the aromatic ringe0
Value
9-methoxy-10, 11-methylenedioxye0
Comparator
gardneraminee0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Gardneria multiflora
Gardneria multiflora · TaxonXufanc · CC BY-SA 4.0 · Wikimedia Commons ↗

Verbatim

e0

“Its oxygenation pattern on the aromatic ring was revealed to be 9-methoxy-10, 11-methylenedioxy and is different from that of gardneramine.”

✓ located verbatim in the source · abstract, characters 147–286 · show in text ↑
e1

“Gardneria multiflora”

✓ located verbatim in the source · abstract, characters 91–111 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

Spectral comparison determined the structure of 18-demethoxygardfloramine.

Taxon
Gardneria multifloraGardneria multiflorae1
Outcome
structure of another minor alkaloid, 18-demethoxygardfloraminee0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Gardneria multiflora
Gardneria multiflora · TaxonXufanc · CC BY-SA 4.0 · Wikimedia Commons ↗

Verbatim

e0

“The structure of another minor alkaloid, 18-demethoxygardfloramine (2) was also determined by comparing the 13C-NMR spectra of 1 and 2.”

✓ located verbatim in the source · abstract, characters 287–422 · show in text ↑
e1

“Gardneria multiflora”

✓ located verbatim in the source · abstract, characters 91–111 · show in text ↑