Paper · 2008 · Molecules

Contribution to the Analysis of the Essential Oil of Helichrysum italicum (Roth) G. Don. – Determination of Ester Bonded Acids and Phenols

Josip Mastelić; Olivera Politeo; Igor Jerković

18
claims
35
verbatim quotes
52
citations
2
research areas
✓
Open access · cc-by

Abstract

The essential oil of Helichrysum italicum (Roth) G. Don (everlasting or Immortelle essential oil) was isolated by hydrodistillation and analysed by GC and GCMS. Forty four compounds were identified. The main components were alpha-pinene(12.8%), 2-methyl-cyclohexyl pentanoate (11.1 %), neryl acetate (10.4%), 1,7-di-epi-alpha-cedrene (6.8%) and other compounds. The oil was fractionated and ester-containing fraction was hydrolysed with KOH/H(2)SO(4). The liberated volatiles were analysed by GC and GC-MS: three phenols and twenty seven volatile carboxylic acids were identified[70% low fatty acids (C(2)-C(5)), 15% C(10)-C(12) acids and 15% other acids]. The main acids were acetic acid (24.3%) propanoic acid (17.2%), 2-methylpropanoic acid (11.4%),dodecanoic acid (8.7%), 2-methylbutanoic acid (8.3%), (Z)-2-methylbutenoic acid(5.1%) and decanoic acid (4.6%). With respect to the identified bonded carboxylic acids,the minimal number of esters in the oil was twenty seven, but their overall quantity was probably larger due to different possible combinations of alcohols with acids to form esters. On the other hand, only six main esters were identified in the oil before fractionation and hydrolysis.

Abstract from the paper’s OpenAlex record; open copy licensed cc-by. Read at the source ↗

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Claims 18

Observationobservedoriginal resultmeasured

Claim · model-written summary

Forty four compounds were identified in Helichrysum italicum essential oil.

Taxon
Helichrysum italicumHelichrysum italicume0
Outcome
Forty four compoundse0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Helichrysum italicum
Helichrysum italicum · Taxon(c) 2005 Zubro · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e0

“The essential oil of Helichrysum italicum (Roth) G. Don (everlasting or Immortelle essential oil) was isolated by hydrodistillation and analysed by GC and GCMS. Forty four compounds were identified.”

✓ located verbatim in the source · abstract, characters 0–198 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

alpha-pinene was a main component of the essential oil at 12.8%.

Taxon
Helichrysum italicumHelichrysum italicumt0
Outcome
alpha-pinenee0
Value
12.8%e0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Helichrysum italicum
Helichrysum italicum · Taxon(c) 2005 Zubro · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e0

“The main components were alpha-pinene(12.8%), 2-methyl-cyclohexyl pentanoate (11.1 %), neryl acetate (10.4%), 1,7-di-epi-alpha-cedrene (6.8%)”

✓ located verbatim in the source · abstract, characters 199–340 · show in text ↑
t0

“Helichrysum italicum”

✓ located verbatim in the source · title, characters 53–73 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

2-methyl-cyclohexyl pentanoate was a main component of the essential oil at 11.1 %.

Taxon
Helichrysum italicumHelichrysum italicumt0
Outcome
2-methyl-cyclohexyl pentanoatee0
Value
11.1 %e0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Helichrysum italicum
Helichrysum italicum · Taxon(c) 2005 Zubro · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e0

“The main components were alpha-pinene(12.8%), 2-methyl-cyclohexyl pentanoate (11.1 %), neryl acetate (10.4%), 1,7-di-epi-alpha-cedrene (6.8%)”

✓ located verbatim in the source · abstract, characters 199–340 · show in text ↑
t0

“Helichrysum italicum”

✓ located verbatim in the source · title, characters 53–73 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

neryl acetate was a main component of the essential oil at 10.4%.

Taxon
Helichrysum italicumHelichrysum italicumt0
Outcome
neryl acetatee0
Value
10.4%e0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Helichrysum italicum
Helichrysum italicum · Taxon(c) 2005 Zubro · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e0

“The main components were alpha-pinene(12.8%), 2-methyl-cyclohexyl pentanoate (11.1 %), neryl acetate (10.4%), 1,7-di-epi-alpha-cedrene (6.8%)”

✓ located verbatim in the source · abstract, characters 199–340 · show in text ↑
t0

“Helichrysum italicum”

✓ located verbatim in the source · title, characters 53–73 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

1,7-di-epi-alpha-cedrene was a main component of the essential oil at 6.8%.

Taxon
Helichrysum italicumHelichrysum italicumt0
Outcome
1,7-di-epi-alpha-cedrenee0
Value
6.8%e0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Helichrysum italicum
Helichrysum italicum · Taxon(c) 2005 Zubro · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e0

“The main components were alpha-pinene(12.8%), 2-methyl-cyclohexyl pentanoate (11.1 %), neryl acetate (10.4%), 1,7-di-epi-alpha-cedrene (6.8%)”

✓ located verbatim in the source · abstract, characters 199–340 · show in text ↑
t0

“Helichrysum italicum”

✓ located verbatim in the source · title, characters 53–73 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

Three phenols and twenty seven volatile carboxylic acids were identified after hydrolysis.

Taxon
Helichrysum italicumHelichrysum italicumt0
Outcome
three phenols and twenty seven volatile carboxylic acidse0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Helichrysum italicum
Helichrysum italicum · Taxon(c) 2005 Zubro · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e0

“three phenols and twenty seven volatile carboxylic acids were identified”

✓ located verbatim in the source · abstract, characters 507–579 · show in text ↑
t0

“Helichrysum italicum”

✓ located verbatim in the source · title, characters 53–73 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

low fatty acids (C(2)-C(5)) accounted for 70% of the liberated acids.

Taxon
Helichrysum italicumHelichrysum italicumt0
Outcome
low fatty acids (C(2)-C(5))e0
Value
70%e0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Helichrysum italicum
Helichrysum italicum · Taxon(c) 2005 Zubro · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e0

“70% low fatty acids (C(2)-C(5)), 15% C(10)-C(12) acids and 15% other acids”

✓ located verbatim in the source · abstract, characters 580–654 · show in text ↑
t0

“Helichrysum italicum”

✓ located verbatim in the source · title, characters 53–73 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

C(10)-C(12) acids accounted for 15% of the liberated acids.

Taxon
Helichrysum italicumHelichrysum italicumt0
Outcome
C(10)-C(12) acidse0
Value
15%e0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Helichrysum italicum
Helichrysum italicum · Taxon(c) 2005 Zubro · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e0

“70% low fatty acids (C(2)-C(5)), 15% C(10)-C(12) acids and 15% other acids”

✓ located verbatim in the source · abstract, characters 580–654 · show in text ↑
t0

“Helichrysum italicum”

✓ located verbatim in the source · title, characters 53–73 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

other acids accounted for 15% of the liberated acids.

Taxon
Helichrysum italicumHelichrysum italicumt0
Outcome
other acidse0
Value
15%e0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Helichrysum italicum
Helichrysum italicum · Taxon(c) 2005 Zubro · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e0

“70% low fatty acids (C(2)-C(5)), 15% C(10)-C(12) acids and 15% other acids”

✓ located verbatim in the source · abstract, characters 580–654 · show in text ↑
t0

“Helichrysum italicum”

✓ located verbatim in the source · title, characters 53–73 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

acetic acid was a main acid at 24.3%.

Taxon
Helichrysum italicumHelichrysum italicumt0
Outcome
acetic acide0
Value
24.3%e0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Helichrysum italicum
Helichrysum italicum · Taxon(c) 2005 Zubro · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e0

“The main acids were acetic acid (24.3%) propanoic acid (17.2%), 2-methylpropanoic acid (11.4%),dodecanoic acid (8.7%), 2-methylbutanoic acid (8.3%), (Z)-2-methylbutenoic acid(5.1%) and decanoic acid (4.6%)”

✓ located verbatim in the source · abstract, characters 657–862 · show in text ↑
t0

“Helichrysum italicum”

✓ located verbatim in the source · title, characters 53–73 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

propanoic acid was a main acid at 17.2%.

Taxon
Helichrysum italicumHelichrysum italicumt0
Outcome
propanoic acide0
Value
17.2%e0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Helichrysum italicum
Helichrysum italicum · Taxon(c) 2005 Zubro · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e0

“The main acids were acetic acid (24.3%) propanoic acid (17.2%), 2-methylpropanoic acid (11.4%),dodecanoic acid (8.7%), 2-methylbutanoic acid (8.3%), (Z)-2-methylbutenoic acid(5.1%) and decanoic acid (4.6%)”

✓ located verbatim in the source · abstract, characters 657–862 · show in text ↑
t0

“Helichrysum italicum”

✓ located verbatim in the source · title, characters 53–73 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

2-methylpropanoic acid was a main acid at 11.4%.

Taxon
Helichrysum italicumHelichrysum italicumt0
Outcome
2-methylpropanoic acide0
Value
11.4%e0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Helichrysum italicum
Helichrysum italicum · Taxon(c) 2005 Zubro · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e0

“The main acids were acetic acid (24.3%) propanoic acid (17.2%), 2-methylpropanoic acid (11.4%),dodecanoic acid (8.7%), 2-methylbutanoic acid (8.3%), (Z)-2-methylbutenoic acid(5.1%) and decanoic acid (4.6%)”

✓ located verbatim in the source · abstract, characters 657–862 · show in text ↑
t0

“Helichrysum italicum”

✓ located verbatim in the source · title, characters 53–73 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

dodecanoic acid was a main acid at 8.7%.

Taxon
Helichrysum italicumHelichrysum italicumt0
Outcome
dodecanoic acide0
Value
8.7%e0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Helichrysum italicum
Helichrysum italicum · Taxon(c) 2005 Zubro · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e0

“The main acids were acetic acid (24.3%) propanoic acid (17.2%), 2-methylpropanoic acid (11.4%),dodecanoic acid (8.7%), 2-methylbutanoic acid (8.3%), (Z)-2-methylbutenoic acid(5.1%) and decanoic acid (4.6%)”

✓ located verbatim in the source · abstract, characters 657–862 · show in text ↑
t0

“Helichrysum italicum”

✓ located verbatim in the source · title, characters 53–73 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

2-methylbutanoic acid was a main acid at 8.3%.

Taxon
Helichrysum italicumHelichrysum italicumt0
Outcome
2-methylbutanoic acide0
Value
8.3%e0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Helichrysum italicum
Helichrysum italicum · Taxon(c) 2005 Zubro · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e0

“The main acids were acetic acid (24.3%) propanoic acid (17.2%), 2-methylpropanoic acid (11.4%),dodecanoic acid (8.7%), 2-methylbutanoic acid (8.3%), (Z)-2-methylbutenoic acid(5.1%) and decanoic acid (4.6%)”

✓ located verbatim in the source · abstract, characters 657–862 · show in text ↑
t0

“Helichrysum italicum”

✓ located verbatim in the source · title, characters 53–73 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

(Z)-2-methylbutenoic acid was a main acid at 5.1%.

Taxon
Helichrysum italicumHelichrysum italicumt0
Outcome
(Z)-2-methylbutenoic acide0
Value
5.1%e0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Helichrysum italicum
Helichrysum italicum · Taxon(c) 2005 Zubro · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e0

“The main acids were acetic acid (24.3%) propanoic acid (17.2%), 2-methylpropanoic acid (11.4%),dodecanoic acid (8.7%), 2-methylbutanoic acid (8.3%), (Z)-2-methylbutenoic acid(5.1%) and decanoic acid (4.6%)”

✓ located verbatim in the source · abstract, characters 657–862 · show in text ↑
t0

“Helichrysum italicum”

✓ located verbatim in the source · title, characters 53–73 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

decanoic acid was a main acid at 4.6%.

Taxon
Helichrysum italicumHelichrysum italicumt0
Outcome
decanoic acide0
Value
4.6%e0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Helichrysum italicum
Helichrysum italicum · Taxon(c) 2005 Zubro · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e0

“The main acids were acetic acid (24.3%) propanoic acid (17.2%), 2-methylpropanoic acid (11.4%),dodecanoic acid (8.7%), 2-methylbutanoic acid (8.3%), (Z)-2-methylbutenoic acid(5.1%) and decanoic acid (4.6%)”

✓ located verbatim in the source · abstract, characters 657–862 · show in text ↑
t0

“Helichrysum italicum”

✓ located verbatim in the source · title, characters 53–73 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

The oil contained at least twenty seven esters inferred from identified bonded acids.

Taxon
Helichrysum italicumHelichrysum italicumt0
Outcome
esters in the oile0
Value
twenty sevene0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Helichrysum italicum
Helichrysum italicum · Taxon(c) 2005 Zubro · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e0

“With respect to the identified bonded carboxylic acids,the minimal number of esters in the oil was twenty seven”

✓ located verbatim in the source · abstract, characters 864–975 · show in text ↑
t0

“Helichrysum italicum”

✓ located verbatim in the source · title, characters 53–73 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

Only six main esters were identified before fractionation and hydrolysis.

Taxon
Helichrysum italicumHelichrysum italicumt0
Outcome
main esterse0
Value
sixe0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Helichrysum italicum
Helichrysum italicum · Taxon(c) 2005 Zubro · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e0

“only six main esters were identified in the oil before fractionation and hydrolysis”

✓ located verbatim in the source · abstract, characters 1121–1204 · show in text ↑
t0

“Helichrysum italicum”

✓ located verbatim in the source · title, characters 53–73 · show in text ↑