Paper · 2015 · Revista Brasileira de Ciência do Solo

PHYTOAVAILABILITY OF COPPER IN INDUSTRIAL BY-PRODUCTS AND MINERAL FERTILIZERS

Camila Prado Cenciani de Souza; Cleide Aparecida de Abreu; José Francisco da Cunha; et al.

5
claims
6
verbatim quotes
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citations
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research areas
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Open access · cc-by

Abstract

Alternative copper (Cu) sources could be used in fertilizer production, although the bioavailability of copper in these materials is unknown. The objective of this study was to evaluate the extractants neutral ammonium citrate (NAC), 2 % citric acid, 1 % acetic acid, 10 % HCl, 10 % H2SO4, buffer solution pH 6.0, DTPA, EDTA, water, and hot water in the quantification of available Cu content in several sources, relating them to the relative agronomic efficiency (RAE) of wheat grown in a clayey Latossolo Vermelho eutrófico (Oxisol) and Neossolo Quartzarênico (Typic Quartzipsamment). Copper was applied at the rate of 1.5 mg kg-1 as scrap slag, brass slag, Cu ore, granulated copper, and copper sulfate. The extractants 10 % HCl, 10 % H2SO4, and NAC extracted higher Cu concentrations. The RAE values of brass slag and Cu ore were similar to or higher than those of Cu sulfate and granulated Cu. Solubility in the 2nd NAC extractant, officially required for mineral fertilizers with Cu, was lower than 60 % for the scrap slag, Cu ore, and granulated copper sources. This fact indicates that adoption of the NAC extractant may be ineffective for industrial by-products, although no extractant was more efficient in predicting Cu availability for wheat fertilized with the Cu sources tested.

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Claims 5

Observationobservedoriginal resultmeasured

Claim · model-written summary

The extractants 10% HCl, 10% H2SO4 and NAC extracted higher Cu concentrations.

Outcome
Cu concentrationse0
Direction
highere0
Qualifier
10 % HCl, 10 % H2SO4, and NACe0

Not reportedTaxon

Verbatim

e0

“The extractants 10 % HCl, 10 % H2SO4, and NAC extracted higher Cu concentrations”

✓ located verbatim in the source · abstract, characters 707–787 · show in text ↑

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Intervention effectobservedoriginal resultpositivemeasured

Claim · model-written summary

The RAE of brass slag and Cu ore was similar to or higher than that of Cu sulfate and granulated Cu.

Treatment
brass slag and Cu oree1
Outcome
RAE valuese1
Direction
similar to or highere1
Comparator
Cu sulfate and granulated Cue1

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Triticum aestivum
Triticum aestivum · TaxonRasbak · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e1

“The RAE values of brass slag and Cu ore were similar to or higher than those of Cu sulfate and granulated Cu”

✓ located verbatim in the source · abstract, characters 789–897 · show in text ↑
e5

“relating them to the relative agronomic efficiency (RAE) of wheat grown in a clayey Latossolo Vermelho eutrófico (Oxisol)”

✓ located verbatim in the source · abstract, characters 413–534 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

Copper solubility in the second NAC extractant was lower than 60% for scrap slag, Cu ore and granulated copper.

Outcome
Solubility in the 2nd NAC extractante2
Direction
lower thane2
Value
60 %e2
Qualifier
scrap slag, Cu ore, and granulated copper sourcese2

Not reportedTaxon

Verbatim

e2

“Solubility in the 2nd NAC extractant, officially required for mineral fertilizers with Cu, was lower than 60 % for the scrap slag, Cu ore, and granulated copper sources”

✓ located verbatim in the source · abstract, characters 899–1067 · show in text ↑

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Recommendationauthor interpretationoriginal resultnegativebasis n/a

Claim · model-written summary

Adoption of the NAC extractant may be ineffective for industrial by-products.

Outcome
adoption of the NAC extractante3

Not reportedTaxon

Verbatim

e3

“This fact indicates that adoption of the NAC extractant may be ineffective for industrial by-products”

✓ located verbatim in the source · abstract, characters 1069–1170 · show in text ↑

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Observationobservedoriginal resultno effectmeasured

Claim · model-written summary

No extractant was more efficient than the others in predicting Cu availability for wheat.

Outcome
predicting Cu availabilitye4
Qualifier
no extractant was more efficiente4

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Triticum aestivum
Triticum aestivum · TaxonRasbak · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e4

“although no extractant was more efficient in predicting Cu availability for wheat fertilized with the Cu sources tested”

✓ located verbatim in the source · abstract, characters 1172–1291 · show in text ↑