Paper · 2025 · European Food Research and Technology

Volatile organic compound profile of roasted and unroasted fine aroma cocoa genotypes from Peru

Sandy Rubith Chapa-Gonza; Natalie Verónika Rondinel-Mendoza; Pedro Javier Mansilla-Córdova; et al.

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Open access · cc-by

Abstract

Abstract Cocoa ( Theobroma cacao L.) is one of Peru’s main export products. In the last years, the production of fine aroma cocoa has increased, and the market has preference for them instead of cultivar clones like CCN51. Fine aroma cocoa is a heterogeneous population, but some genotypes has started to be selected. This study aimed to evaluate the chemical properties and volatile organic compound (VOC) profile of different fine aroma cocoa genotypes and CCN51. The chemical composition—including moisture, fat, protein, ash, carbohydrate, pH, fermentation index and total phenolic compounds—was determined using standard analytical procedures. VOC were analyzed using SPME/GC-MS. Protein content varied among genotypes, with ABL01 showing the highest percentage. Fat content also ranged widely, with ABL01 and JBB04 representing the highest and the lowest values, respectively. Significant differences in ash and carbohydrate contents were also observed. The pH values suggested that fermentation was generally adequate, although some genotypes showed potential deficiencies. Fine aroma cocoa (FAC) genotypes exhibited lower phenolic compound content compared to the commercial clone CCN51. VOC analysis revealed compositional differences, with certain compounds contributing more prominently to the variation of specific genetic groups profile. These findings suggest that there exists a huge variability in VOC and other chemical properties of fine aroma cocoa genotypes and it is expected that data generated about roasted and no roasted beans will be useful for future research.

Abstract from the paper’s OpenAlex record; open copy licensed cc-by. Read at the source ↗

The text the model read, with the source record’s inline markup (italics, sub- and superscripts) rendered and its character entities decoded; quote offsets refer to the raw text.

Claims 7

Observationobservedoriginal resultmeasured

Claim · model-written summary

ABL01 had the highest protein percentage among cocoa genotypes.

Material
ABL01e0
Outcome
Protein contente0
Direction
higheste0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Theobroma cacao
Theobroma cacao · TaxonLuisovalles · CC BY 3.0 · Wikimedia Commons ↗

Verbatim

e0

“Protein content varied among genotypes, with ABL01 showing the highest percentage.”

✓ located verbatim in the source · abstract, characters 685–767 · show in text ↑
t0

“Cocoa”

✓ located after whitespace/quote normalisation · title, characters 70–75 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

ABL01 had the highest fat content.

Material
ABL01e0
Outcome
Fat contente0
Direction
higheste0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Theobroma cacao
Theobroma cacao · TaxonLuisovalles · CC BY 3.0 · Wikimedia Commons ↗

Verbatim

e0

“Fat content also ranged widely, with ABL01 and JBB04 representing the highest and the lowest values, respectively.”

✓ located verbatim in the source · abstract, characters 768–882 · show in text ↑
t0

“Cocoa”

✓ located after whitespace/quote normalisation · title, characters 70–75 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

JBB04 had the lowest fat content.

Material
JBB04e0
Outcome
Fat contente0
Direction
loweste0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Theobroma cacao
Theobroma cacao · TaxonLuisovalles · CC BY 3.0 · Wikimedia Commons ↗

Verbatim

e0

“Fat content also ranged widely, with ABL01 and JBB04 representing the highest and the lowest values, respectively.”

✓ located verbatim in the source · abstract, characters 768–882 · show in text ↑
t0

“Cocoa”

✓ located after whitespace/quote normalisation · title, characters 70–75 · show in text ↑
Observationobservedoriginal resultsignificant (as stated)measured

Claim · model-written summary

Ash and carbohydrate contents differed significantly among genotypes.

Outcome
ash and carbohydrate contentse0

Not reportedDirection

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Theobroma cacao
Theobroma cacao · TaxonLuisovalles · CC BY 3.0 · Wikimedia Commons ↗

Verbatim

e0

“Significant differences in ash and carbohydrate contents were also observed.”

✓ located verbatim in the source · abstract, characters 883–959 · show in text ↑
t0

“Cocoa”

✓ located after whitespace/quote normalisation · title, characters 70–75 · show in text ↑
Observationauthor interpretationoriginal resultmeasured

Claim · model-written summary

pH suggested generally adequate fermentation, with possible deficiencies in some genotypes.

Outcome
fermentation was generally adequate, although some genotypes showed potential deficienciese0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Theobroma cacao
Theobroma cacao · TaxonLuisovalles · CC BY 3.0 · Wikimedia Commons ↗

Verbatim

e0

“The pH values suggested that fermentation was generally adequate, although some genotypes showed potential deficiencies.”

✓ located verbatim in the source · abstract, characters 960–1080 · show in text ↑
t0

“Cocoa”

✓ located after whitespace/quote normalisation · title, characters 70–75 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

Fine aroma cocoa genotypes had lower phenolic compound content than CCN51.

Material
Fine aroma cocoa (FAC) genotypese0
Outcome
phenolic compound contente0
Direction
lowere0
Comparator
commercial clone CCN51e0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Theobroma cacao
Theobroma cacao · TaxonLuisovalles · CC BY 3.0 · Wikimedia Commons ↗

Verbatim

e0

“Fine aroma cocoa (FAC) genotypes exhibited lower phenolic compound content compared to the commercial clone CCN51.”

✓ located verbatim in the source · abstract, characters 1081–1195 · show in text ↑
t0

“Cocoa”

✓ located after whitespace/quote normalisation · title, characters 70–75 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

Volatile composition differed among cocoa genetic groups.

Outcome
compositional differencese0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Theobroma cacao
Theobroma cacao · TaxonLuisovalles · CC BY 3.0 · Wikimedia Commons ↗

Verbatim

e0

“VOC analysis revealed compositional differences, with certain compounds contributing more prominently to the variation of specific genetic groups profile.”

✓ located verbatim in the source · abstract, characters 1196–1350 · show in text ↑
t0

“Cocoa”

✓ located after whitespace/quote normalisation · title, characters 70–75 · show in text ↑