Paper · 2022 · Agronomy

Bioavailability, Speciation, and Crop Responses to Copper, Zinc, and Boron Fertilization in South-Central Saskatchewan Soil

Noabur Rahman; Jeff Schoenau

11
claims
18
verbatim quotes
8
citations
2
research areas
✓
Open access · cc-by

Abstract

An appropriate fertilization strategy is essential for improving micronutrient supply, crop nutrition, yield and quality. Comparative effects of different application strategies of micronutrient fertilizer were evaluated in two contrasting sites/soils (upper slope Chernozem and lower slope Solonetz) within a farm field located in the Brown soil zone of Saskatchewan, Canada. The study objective was to examine the impact of Cu, Zn, and B fertilizer application strategies on their mobility, bioavailability and fate in the soil as well as crop yield responses. The application strategies were broadcast, broadcast and incorporation, seed row banding, and foliar application of Cu, Zn, and B on wheat, pea, and canola, respectively. The study was laid out in a randomized complete block design (RCBD) with four treatment replicates for a specific crop and site. Crop biomass yields were not significantly influenced by micronutrient placement strategies at both sites. Pea tissue Zn concentration (35.2 mg Zn kg−1 grain and 5.15 mg Zn kg−1 straw) was increased by broadcast and incorporation of Zn sulfate on the Solonetz soil. Residual levels of soil extractable available Cu were increased significantly to 3.18 mg Cu kg−1 soil at Chernozem and 2.53 mg Cu kg−1 soil Solonetz site with the seed row banding of Cu sulfate. The PRS™-probe supply of Cu (1.84 µm Cu/cm2) and Zn (1.18 µm Zn/cm2) were significantly higher with broadcast application of corresponding micronutrient fertilizer in the Chernozem soil. Both the chemical and spectroscopic speciation revealed that carbonate associated Cu and Zn were dominant species that are likely to control the bioavailability of these micronutrients under field conditions.

Abstract from the paper’s OpenAlex record; open copy licensed cc-by. Read at the source ↗

The text the model read, with the source record’s inline markup (italics, sub- and superscripts) rendered and its character entities decoded; quote offsets refer to the raw text.

Claims 11

Intervention effectobservedoriginal resultno effectnot significant (as stated)measured

Claim · model-written summary

wheat biomass yield was not significantly influenced by micronutrient placement.

Treatment
micronutrient placement strategiese1
Outcome
Crop biomass yieldse1
Direction
not significantly influencede1

Not reportedComparator

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Triticum aestivum
Triticum aestivum · TaxonRasbak · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e0

“The application strategies were broadcast, broadcast and incorporation, seed row banding, and foliar application of Cu, Zn, and B on wheat, pea, and canola, respectively”

✓ located verbatim in the source · abstract, characters 563–732 · show in text ↑
e1

“Crop biomass yields were not significantly influenced by micronutrient placement strategies at both sites”

✓ located verbatim in the source · abstract, characters 863–968 · show in text ↑
Intervention effectobservedoriginal resultno effectnot significant (as stated)measured

Claim · model-written summary

pea biomass yield was not significantly influenced by micronutrient placement.

Treatment
micronutrient placement strategiese1
Outcome
Crop biomass yieldse1
Direction
not significantly influencede1

Not reportedComparator

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Lathyrus oleraceus
Lathyrus oleraceus · TaxonRenee Comet (photographer) AV Number: AV-9400-4164 · Public domain · Wikimedia Commons ↗

Verbatim

e0

“The application strategies were broadcast, broadcast and incorporation, seed row banding, and foliar application of Cu, Zn, and B on wheat, pea, and canola, respectively”

✓ located verbatim in the source · abstract, characters 563–732 · show in text ↑
e1

“Crop biomass yields were not significantly influenced by micronutrient placement strategies at both sites”

✓ located verbatim in the source · abstract, characters 863–968 · show in text ↑
Intervention effectobservedoriginal resultno effectnot significant (as stated)measured

Claim · model-written summary

canola biomass yield was not significantly influenced by micronutrient placement.

Treatment
micronutrient placement strategiese1
Outcome
Crop biomass yieldse1
Direction
not significantly influencede1

Not reportedComparator

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Brassica napus var. napus
Brassica napus var. napus · Taxoncontri from Yonezawa-Shi, Yamagata, Japan · CC BY-SA 2.0 · Wikimedia Commons ↗

Verbatim

e0

“The application strategies were broadcast, broadcast and incorporation, seed row banding, and foliar application of Cu, Zn, and B on wheat, pea, and canola, respectively”

✓ located verbatim in the source · abstract, characters 563–732 · show in text ↑
e1

“Crop biomass yields were not significantly influenced by micronutrient placement strategies at both sites”

✓ located verbatim in the source · abstract, characters 863–968 · show in text ↑
Intervention effectobservedoriginal resultpositivemeasured

Claim · model-written summary

Broadcast incorporation of Zn sulfate increased pea grain Zn concentration to 35.2 mg Zn kg−1 grain.

Organ / stage
graine0
Treatment
broadcast and incorporation of Zn sulfatee0
Outcome
tissue Zn concentratione0
Direction
increasede0
Value
35.2 mg Zn kg−1 graine0
Setting
Solonetz soile0

Not reportedComparator

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Lathyrus oleraceus
Lathyrus oleraceus · TaxonRenee Comet (photographer) AV Number: AV-9400-4164 · Public domain · Wikimedia Commons ↗

Verbatim

e0

“Pea tissue Zn concentration (35.2 mg Zn kg−1 grain and 5.15 mg Zn kg−1 straw) was increased by broadcast and incorporation of Zn sulfate on the Solonetz soil”

✓ located verbatim in the source · abstract, characters 970–1127 · show in text ↑
Intervention effectobservedoriginal resultpositivemeasured

Claim · model-written summary

Broadcast incorporation of Zn sulfate increased pea straw Zn concentration to 5.15 mg Zn kg−1 straw.

Organ / stage
strawe0
Treatment
broadcast and incorporation of Zn sulfatee0
Outcome
tissue Zn concentratione0
Direction
increasede0
Value
5.15 mg Zn kg−1 strawe0
Setting
Solonetz soile0

Not reportedComparator

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Lathyrus oleraceus
Lathyrus oleraceus · TaxonRenee Comet (photographer) AV Number: AV-9400-4164 · Public domain · Wikimedia Commons ↗

Verbatim

e0

“Pea tissue Zn concentration (35.2 mg Zn kg−1 grain and 5.15 mg Zn kg−1 straw) was increased by broadcast and incorporation of Zn sulfate on the Solonetz soil”

✓ located verbatim in the source · abstract, characters 970–1127 · show in text ↑
Intervention effectobservedoriginal resultpositivesignificant (as stated)measured

Claim · model-written summary

Seed row banding of Cu sulfate significantly increased extractable soil Cu at Chernozem.

Treatment
seed row banding of Cu sulfatee1
Outcome
soil extractable available Cue1
Direction
increasede1
Value
3.18 mg Cu kg−1 soile1
Setting
Chernozeme1

Not reportedComparator

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Triticum aestivum
Triticum aestivum · TaxonRasbak · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e0

“seed row banding, and foliar application of Cu, Zn, and B on wheat, pea, and canola, respectively”

✓ located verbatim in the source · abstract, characters 635–732 · show in text ↑
e1

“Residual levels of soil extractable available Cu were increased significantly to 3.18 mg Cu kg−1 soil at Chernozem and 2.53 mg Cu kg−1 soil Solonetz site with the seed row banding of Cu sulfate”

✓ located verbatim in the source · abstract, characters 1129–1322 · show in text ↑
Intervention effectobservedoriginal resultpositivesignificant (as stated)measured

Claim · model-written summary

Seed row banding of Cu sulfate significantly increased extractable soil Cu at Solonetz.

Treatment
seed row banding of Cu sulfatee1
Outcome
soil extractable available Cue1
Direction
increasede1
Value
2.53 mg Cu kg−1 soile1
Setting
Solonetze1

Not reportedComparator

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Triticum aestivum
Triticum aestivum · TaxonRasbak · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e0

“seed row banding, and foliar application of Cu, Zn, and B on wheat, pea, and canola, respectively”

✓ located verbatim in the source · abstract, characters 635–732 · show in text ↑
e1

“Residual levels of soil extractable available Cu were increased significantly to 3.18 mg Cu kg−1 soil at Chernozem and 2.53 mg Cu kg−1 soil Solonetz site with the seed row banding of Cu sulfate”

✓ located verbatim in the source · abstract, characters 1129–1322 · show in text ↑
Intervention effectobservedoriginal resultpositivesignificant (as stated)measured

Claim · model-written summary

Broadcast fertilizer increased PRS probe Cu supply in Chernozem soil.

Treatment
broadcast application of corresponding micronutrient fertilizere1
Outcome
PRS™-probe supply of Cue1
Direction
highere1
Value
1.84 µm Cu/cm2e1
Setting
Chernozem soile1

Not reportedComparator

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Triticum aestivum
Triticum aestivum · TaxonRasbak · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e0

“Cu, Zn, and B on wheat, pea, and canola, respectively”

✓ located verbatim in the source · abstract, characters 679–732 · show in text ↑
e1

“The PRS™-probe supply of Cu (1.84 µm Cu/cm2) and Zn (1.18 µm Zn/cm2) were significantly higher with broadcast application of corresponding micronutrient fertilizer in the Chernozem soil”

✓ located verbatim in the source · abstract, characters 1324–1509 · show in text ↑
Intervention effectobservedoriginal resultpositivesignificant (as stated)measured

Claim · model-written summary

Broadcast fertilizer increased PRS probe Zn supply in Chernozem soil.

Treatment
broadcast application of corresponding micronutrient fertilizere1
Outcome
Zne1
Direction
highere1
Value
1.18 µm Zn/cm2e1
Setting
Chernozem soile1

Not reportedComparator

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Lathyrus oleraceus
Lathyrus oleraceus · TaxonRenee Comet (photographer) AV Number: AV-9400-4164 · Public domain · Wikimedia Commons ↗

Verbatim

e0

“Cu, Zn, and B on wheat, pea, and canola, respectively”

✓ located verbatim in the source · abstract, characters 679–732 · show in text ↑
e1

“The PRS™-probe supply of Cu (1.84 µm Cu/cm2) and Zn (1.18 µm Zn/cm2) were significantly higher with broadcast application of corresponding micronutrient fertilizer in the Chernozem soil”

✓ located verbatim in the source · abstract, characters 1324–1509 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

Carbonate associated Cu and Zn were dominant soil species.

Outcome
carbonate associated Cu and Zn were dominant speciese0

Not reportedTaxonDirection

Verbatim

e0

“Both the chemical and spectroscopic speciation revealed that carbonate associated Cu and Zn were dominant species that are likely to control the bioavailability of these micronutrients under field conditions”

✓ located verbatim in the source · abstract, characters 1511–1718 · show in text ↑
Mechanismauthor interpretationoriginal resultmeasured

Claim · model-written summary

Authors infer carbonate associated Cu and Zn likely control micronutrient bioavailability.

Outcome
bioavailability of these micronutrientse0
Qualifier
carbonate associated Cu and Zne0

Not reportedTaxon

Verbatim

e0

“Both the chemical and spectroscopic speciation revealed that carbonate associated Cu and Zn were dominant species that are likely to control the bioavailability of these micronutrients under field conditions”

✓ located verbatim in the source · abstract, characters 1511–1718 · show in text ↑

copper atom · nutrient: content · Triticum aestivum (wheat)Results differ

36 papers: 24 positive, 12 negative or no effect

23 papers in the same direction as this paper · 12 in the opposite direction

  1. no effect
  2. negative
  3. negative

32 papers more in this group

See all 36 papers →

sulfate · nutrient: content · Triticum aestivum (wheat)Positive and negative results

8 papers: 7 positive, 1 negative or no effect

6 papers in the same direction as this paper · 1 in the opposite direction

  1. no effect
  2. positive
  3. positive

4 papers more in this group

See all 8 papers →

zinc atom · nutrient: content · Lathyrus oleraceus (pea)Positive and negative results

15 papers: 12 positive, 3 negative or no effect

11 papers in the same direction as this paper · 3 in the opposite direction

  1. negative
  2. no effect
  3. negative

11 papers more in this group

See all 15 papers →

sulfate · nutrient: content · Lathyrus oleraceus (pea)Results agree

2 papers: 2 positive, 0 negative or no effect

1 paper in the same direction as this paper

  1. positive
See all 2 papers →

transplanting · nutrient: content · Lathyrus oleraceus (pea)Positive and negative results

4 papers: 1 positive, 3 negative or no effect

3 in the opposite direction

  1. negative
  2. no effect
  3. no effect
See all 4 papers →

micronutrient · yield · Brassica napus (oilseed rape)Positive and negative results

12 papers: 10 positive, 2 negative or no effect

1 paper in the same direction as this paper · 10 in the opposite direction

  1. positive
  2. positive
  3. positive

8 papers more in this group

See all 12 papers →

micronutrient · yield · Lathyrus oleraceus (pea)Positive and negative results

12 papers: 10 positive, 2 negative or no effect

1 paper in the same direction as this paper · 10 in the opposite direction

  1. positive
  2. positive
  3. positive

8 papers more in this group

See all 12 papers →

transplanting · nutrient: content · Triticum aestivum (wheat)Positive and negative results

16 papers: 10 positive, 6 negative or no effect

9 papers in the same direction as this paper · 5 in the opposite direction · 1 reporting no difference from an alternative

  1. negative
  2. negative
  3. negative

12 papers more in this group

See all 16 papers →

8 of 13 groups shown: named compounds and organisms first, then groups whose results differ (checked claim by claim), then those with positive and negative results, then the smaller groups.

Claims are grouped by organism, treatment and what was measured or targeted. A paper counts as positive when any of its claims in the group is positive.